The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (N-compounds) / Nitriles / HC5N / Coupeaud(2007)_300K_200-292nm

DATAFILE: HC5N_Coupeaud(2007)_300K_200-292nm.txt
NAME: cyanodiacetylene, 2,4-pentadiynenitrile, 1-cyano-1,3-butadiyne
FORMULA: HC5N
AUTHOR(YEAR): Coupeaud(2007)
T: 300K
λ: 200-292nm
BIBLIOGRAPHY: A. Coupeaud, M. Turowski, M. Gronowski, N. Pietri, I. Couturier-Tamburelli, R. Kolos, and J.-P. Aycard, "Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanediacetylene", J. Chem. Phys. 126, 164301(8 pages) (2007); DOI: 10.1063/1.2720842
COMMENTS: Medium-resolution (0.2 nm) absorption measurements using a Shimadzu UV-3100 spectrophotometer

The optical densities have been calibrated to the absolute absorption cross sections in the 200-205-nm range measured by

N. Fray, Y. Bénilan, M.-C. Gazeau, A. Jolly, M. Schwell, E. Arzoumanian, T. Ferradaz, E. Es-Sebbar, and J.-C. Guillemin, Temperature-dependent photoabsorption cross section of cyanodiacetylene in the vacuum UV, J. Geophys. Res, 115 E, E06010 (2010); DOI: 10.1029/2009JE003518,

and are shown in Fig. 1, which has been digitized

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